Preparation of copper nanoparticles coated cellulose films with antibacterial properties through one-step reduction

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• 作者：Baoquan Jia ; Yan Mei ; Li Cheng ; Jinping Zhou ; Lina Zhang
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2012
• 出版时间：June 27, 2012
• 年：2012
• 卷：4
• 期：6
• 页码：2897-2902
• 全文大小：381K
• 年卷期：v.4,no.6(June 27, 2012)
• ISSN：1944-8252

文摘

Regenerated cellulose (RC) films coated with copper (Cu) nanoparticles were prepared from cellulose-cuprammonium solution through coagulation in aq. NaOH and subsequent reduction in aq. NaBH₄. Structure and morphology of the nanocomposite films were characterized with X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM). The results established the migration of Cu²⁺ from the inner to the surface of the RC films during the coagulation of cellulose-cuprammonium solution and the reduction from Cu²⁺ to Cu⁰. Cu nanoparticles were found to be firmly embedded on the surface of the RC films. The RC films coated with Cu nanoparticles showed efficient antibacterial activity against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). The dramatic reduction of viable bacteria could be observed within 0.5 h of exposure, and all of the bacteria were killed within 1 h.

Keywords:

copper nanoparticles; cellulose; nanocomposite film; one-step reduction; antibacterial