Solution-Based Synthesis and Characterization of Lithium-Ion Conducting Phosphate Ceramics for Lithium Metal Batteries

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• 作者：Baris Key ; David J. Schroeder ; Brian J. Ingram ; John T. Vaughey
• 刊名：Chemistry of Materials
• 出版年：2012
• 出版时间：January 24, 2012
• 年：2012
• 卷：24
• 期：2
• 页码：287-293
• 全文大小：486K
• 年卷期：v.24,no.2(January 24, 2012)
• ISSN：1520-5002

文摘

High conductivity solid electrolytes are promising solutions for extremely high energy density battery systems including Li/air and Li/sulfur. Lithium aluminum titanium phosphate (LATP) ceramics have among the highest reported ionic conductivities and are promising candidates as solid electrolytes. Li_1.3Al_0.3Ti_1.7(PO₄)₃ powders were synthesized for the first time via a solution-based method at synthesis temperatures as low as 650 掳C. The ceramic powders are characterized using X-ray powder diffraction, solid state magic angle spinning (MAS) nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The effect of Li and Al local structure and the presence of amorphous and crystalline impurities on electrolyte morphology and sinterability have been studied in detail.

Keywords:

solid electrolyte; battery; LATP; solid state NMR