Synthesis and Reactivity of Bicyclo[3.2.1]octanoid-Derived Cyclopropanes
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- 作者：John R. Goodell ; Jennifer L. Poole ; Aaron B. Beeler ; Jeffrey Aub茅 ; John A. Porco ; Jr.
- 刊名：Journal of Organic Chemistry
- 出版年：2011
- 出版时间：December 2, 2011
- 年：2011
- 卷：76
- 期：23
- 页码：9792-9800
- 全文大小：549K
- 年卷期：v.76,no.23(December 2, 2011)
- ISSN：1520-6904
文摘
Photochemical oxa-di-蟺-methane rearrangement of bicyclo[3.2.1]octanoid scaffolds affords multifunctional, donor鈥揳cceptor cyclopropanes. A related photochemical reaction of an iminium ether substrate uncovered an unprecedented aza-di-蟺-methane rearrangement of a 尾,纬-unsaturated iminium. Donor鈥揳cceptor cyclopropanes have been evaluated as substrates for reactions generating several new chemotypes.