Synthesis of Triangular Metallodendrimers via Coordination-Driven Self-Assembly

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• 作者：Qing Han ; Li-Lei Wang ; Quan-Jie Li ; Guang-Zhen Zhao ; Jiuming He ; Bingjie Hu ; Hongwei Tan ; Zeper Abliz ; Yihua Yu ; Hai-Bo Yang
• 刊名：The Journal of Organic Chemistry
• 出版年：2012
• 出版时间：April 6, 2012
• 年：2012
• 卷：77
• 期：7
• 页码：3426-3432
• 全文大小：369K
• 年卷期：v.77,no.7(April 6, 2012)
• ISSN：1520-6904

文摘

A new family of 60掳 dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel 鈥渢hree-component鈥?triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR (¹H and ³¹P), ¹H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.