Exploitation of Guest Accessible Aliphatic Amine Functionality of a Metal鈥揙rganic Framework for Selective Detection of 2,4,6-Trinitrophenol (TNP) in Water

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• 作者：Soumya Mukherjee ; Aamod V. Desai ; Biplab Manna ; Arif I. Inamdar ; Sujit K. Ghosh
• 刊名：Crystal Growth & Design
• 出版年：2015
• 出版时间：September 2, 2015
• 年：2015
• 卷：15
• 期：9
• 页码：4627-4634
• 全文大小：495K
• ISSN：1528-7505

文摘

Highly selective and sensitive aqueous phase-detection of the well-known nitro explosive environmental pollutant 2,4,6-trinitrophenol (TNP) by a water-stable, porous luminescent metal鈥搊rganic framework has been reported. The presence of a guest accessible aliphatic amine functionality in the MOF channels has been strategically harnessed for serving the purpose of exclusive TNP-sensing in water even in concurrent presence of other nitro aromatic and nitro aliphatic analytes.