Layer-by-Layer Assembly of a Metallomesogen by Dip-Pen Nanolithography
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- 作者：Boya Radha ; Guoliang Liu ; Daniel J. Eichelsdoerfer ; Giridhar U. Kulkarni ; Chad A. Mirkin
- 刊名：ACS Nano
- 出版年：2013
- 出版时间：March 26, 2013
- 年：2013
- 卷：7
- 期：3
- 页码：2602-2609
- 全文大小：513K
- 年卷期：v.7,no.3(March 26, 2013)
- ISSN：1936-086X
文摘
Palladium alkanethiolates are introduced here as a novel liquid ink for dip-pen nanolithography (DPN). These structures exhibit the unusual characteristic of layer-by-layer assembly, allowing one to deposit a desired number of metal ions on a surface, which can subsequently be reduced via thermolysis to form active catalytic structures. Such structures have been used to generate contiguous metallic or conducting polymer nanoscale architectures by electroless deposition.