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• 作者：Lucia Balazs ; Hans J. Breunig ; Enno Lork ; Albert Soran ; and Cristian Silvestru
• 刊名：Inorganic Chemistry
• 出版年：2006
• 出版时间：March 6, 2006
• 年：2006
• 卷：45
• 期：5
• 页码：2341 - 2346
• 全文大小：276K
• 年卷期：v.45,no.5(March 6, 2006)
• ISSN：1520-510X

文摘

R₂Bi-BiR₂ [1; R = 2,6-(Me₂NCH₂)₂C₆H₃], a dibismuthane that exists in different forms in the crystalline state,reacts in air with the formation of the peroxide [R₂Bi]₂(O₂) (2) and partial oxidation of the pendant (dimethylamino)methyl groups, yielding the mononuclear bismuth complex R'R' 'Bi (3) [R' = 2-(Me₂NCH₂)-6-{Me₂N(O)CH₂}C₆H₃;R' ' = 2-(Me₂NCH₂)-6-{O(O)C}C₆H₃].