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• 作者：Hans J. Breunig ; Tobias Borrmann ; Enno Lork ; Ciprian I. Ra ; Uwe Rosenthal
• 刊名：Organometallics
• 出版年：2007
• 出版时间：October 22, 2007
• 年：2007
• 卷：26
• 期：22
• 页码：5364 - 5368
• 全文大小：99K
• 年卷期：v.26,no.22(October 22, 2007)
• ISSN：1520-6041

文摘

Exposure of [W(CO)₅(2,6-Mes₂C₆H₃SbH₂)] (1) in toluene to day light leads to the distibene complex[W(CO)₅{(2,6-Mes₂C₆H₃)₂Sb₂}] (2). [Cp₂Ti{(2,6-Mes₂C₆H₃)₂Sb₂}] (3) is obtained by reaction of [Cp₂Ti{(Me₃Si)₂C₂}] with 2,6-Mes₂C₆H₃SbH₂. The structures of 2 and 3 were determined by single-crystalX-ray diffraction, and DFT calculations were carried out on Me₂Sb₂, [W(CO)₅(Me₂Sb₂)] (2a), and [Cp₂Ti(Me₂Sb₂)] (3a).