Probing the Dipolar Coupling in a Heterospin Endohedral Fullerene–Phthalocyanine Dyad

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• 作者：Shen Zhou ; Masanori Yamamoto ; G. Andrew D. Briggs ; Hiroshi Imahori ; Kyriakos Porfyrakis
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：February 3, 2016
• 年：2016
• 卷：138
• 期：4
• 页码：1313-1319
• 全文大小：474K
• ISSN：1520-5126

文摘

Paramagnetic endohedral fullerenes and phthalocyanine (Pc) complexes are promising building blocks for molecular quantum information processing, for which tunable dipolar coupling is required. We have linked these two spin qubit candidates together and characterized the resulting electron paramagnetic resonance properties, including the spin dipolar coupling between the fullerene spin and the copper spin. Having interpreted the distance-dependent coupling strength quantitatively and further discussed the antiferromagnetic aggregation effect of the CuPc moieties, we demonstrate two ways of tuning the dipolar coupling in such dyad systems: changing the spacer group and adjusting the solution concentration.