Effect of Fluorination on the Properties of a Donor鈥揂cceptor Copolymer for Use in Photovoltaic Cells and Transistors
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- 作者：Hugo Bronstein ; Jarvist M. Frost ; Afshin Hadipour ; Youngju Kim ; Christian B. Nielsen ; Raja Shahid Ashraf ; Barry P. Rand ; Scott Watkins ; Iain McCulloch
- 刊名：Chemistry of Materials
- 出版年：2013
- 出版时间：February 12, 2013
- 年：2013
- 卷：25
- 期：3
- 页码：277-285
- 全文大小：614K
- 年卷期：v.25,no.3(February 12, 2013)
- ISSN：1520-5002
文摘
Two novel indacenodithiophene (IDT) based donor鈥揳cceptor conjugated polymers for use in organic field effect transistors and photovoltaic devices are synthesized and characterized. The effect of inclusion of two fluorine atoms on the acceptor portion of the polymer is thoroughly investigated via a range of techniques. The inductively withdrawing and mesomerically donating properties of the fluorine atoms result in a decrease of the highest occupied molecular orbital (HOMO), with little effect on the lowest unoccupied molecular orbital (LUMO) as demonstrated through density functional theory (DFT) analysis. Inclusion of fluorine atoms also leads to a potentially more planar backbone through inter and intrachain interactions. Use of the novel materials in organic field effect transistor (OFET) and organic photovoltaic (OPV) devices leads to high mobilities around 0.1 cm2/(V s) and solar cell efficiencies around 4.5%.