Enhanced Gas Sorption Properties and Unique Behavior toward Liquid Water in a Pillared-Paddlewheel Metal鈥揙rganic Framework Transmetalated with Ni(II)

详细信息    查看全文

• 作者：Olga Karagiaridi ; Wojciech Bury ; David Fairen-Jimenez ; Christopher E. Wilmer ; Amy A. Sarjeant ; Joseph T. Hupp ; Omar K. Farha
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：October 6, 2014
• 年：2014
• 卷：53
• 期：19
• 页码：10432-10436
• 全文大小：301K
• ISSN：1520-510X

文摘

The synthesis of a permanently porous pillared-paddlewheel metal鈥搊rganic framework (MOF) was achieved through transmetalation of Zn(II) with Ni(II). The MOF can be treated with liquid water, leading to the reversible displacement of 50% of its pillars by water molecules and resulting in a most unusual crystalline and permanently porous structure.