Responsive Nature of 1,2,4,5-Tetrakis(2-pyridylthiomethyl)benzene Toward Group 12 Metal Nitrates: Activity of Coordinated Nitrate in Metal Complexes

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• 作者：Neeru ; Dolly Yadav ; Geeta Tiwari ; Jai Deo Singh ; Raymond J. Butcher
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：June 16, 2014
• 年：2014
• 卷：53
• 期：12
• 页码：5887-5889
• 全文大小：201K
• 年卷期：v.53,no.12(June 16, 2014)
• ISSN：1520-510X

文摘

This study provides a detailed analysis on the responsive behavior of 1,2,4,5-tetrakis(2-pyridylthiomethyl)benzene (L) toward group 12 metal nitrates in both aqueous and nonaqueous media. The ligand L proved to be an environmentally responsive species, and structural investigations of its complexes with respective M(NO₃)₂ (M = Zn, Cd, and Hg) allowed one to remark on the inherent activity of the nitrate ion, resulting in a distinctively higher coordination number and dimensionality to the metal cations.