Factors Affecting DNP NMR in Polycrystalline Diamond Samples

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• 作者：Leah B. Casabianca ; Alexander I. Shames ; Alexander M. Panich ; Olga Shenderova ; Lucio Frydman
• 刊名：Journal of Physical Chemistry C
• 出版年：2011
• 出版时间：October 6, 2011
• 年：2011
• 卷：115
• 期：39
• 页码：19041-19048
• 全文大小：973K
• 年卷期：v.115,no.39(October 6, 2011)
• ISSN：1932-7455

文摘

This work examines several polycrystalline diamond samples for their potential as polarizing agents for dynamic nuclear polarization (DNP) in NMR. Diamond samples of various origin and particle sizes ranging from a few nanometers to micrometers were examined by EPR, solid-state NMR and DNP techniques. A correlation was found between the size of the diamond particles and the electron spin鈥搇attice relaxation time, the ¹³C nuclear spin鈥搇attice relaxation times in room temperature magic-angle-spinning experiments, and the ability of the diamond carbons to be hyperpolarized by irradiating unpaired electrons of inherent defects by microwaves at cryogenic temperatures. As the size of the diamond particles approaches that of bulk diamond, both electron and nuclear relaxation times become longer. NMR signal enhancement through DNP was found to be very efficient only for these larger size diamond samples. The reasons and implications of these results are briefly discussed, in the light of these EPR, DNP, and NMR observations.