Synthesis and X-ray Crystal Structure of [(C5Ph5)CrCl(-Cl)2Tl]2: An Example of the Rare M-
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- 作者：K. Brian Davis ; T. David Harris ; Michael P. Castellani ; James A. Golen ; Arnold L. Rheingold
- 刊名：Organometallics
- 出版年：2007
- 出版时间：September 10, 2007
- 年：2007
- 卷：26
- 期：19
- 页码：4843 - 4845
- 全文大小：100K
- 年卷期：v.26,no.19(September 10, 2007)
- ISSN：1520-6041
文摘
Reaction of solid TlCl with [(C5Ph5)CrCl(
-Cl)]2 inCH2Cl2 solvent yields the dimeric complex [(C5Ph5)CrCl(-Cl)2Tl]2 in 80% isolated yield. The C5H5 and C5Me5 analogues donot react with TlCl, suggesting a steric basis for the reactionof the C5Ph5 material.
-Cl)]2 inCH2Cl2 solvent yields the dimeric complex [(C5Ph5)CrCl(-Cl)2Tl]2 in 80% isolated yield. The C5H5 and C5Me5 analogues donot react with TlCl, suggesting a steric basis for the reactionof the C5Ph5 material.