Catalytic Tandem and One-Pot Dehydrogenation–Alkylation and −Insertion Reactions of Saturated Hydrocarbons with Alcohols and Alkenes

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• 作者：Junghwa Kim ; Nuwan Pannilawithana ; Chae S. Yi
• 刊名：ACS Catalysis
• 出版年：2016
• 出版时间：December 2, 2016
• 年：2016
• 卷：6
• 期：12
• 页码：8395-8398
• 全文大小：408K
• ISSN：2155-5435

文摘

The ruthenium-hydride catalyst has been successfully used for the tandem sp<sup>3sup> C–H dehydrogenation–alkylation reaction of saturated hydrocarbon substrates with alcohols to form the alkyl-substituted alkene and arene products. The analogous one-pot dehydrogenation–insertion of saturated ketones with alkenes and dienes directly yielded synthetically useful 2-alkylphenol and benzopyran products in a highly regio- and stereoselective manner without forming any wasteful byproducts.