Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekul Structures
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- 作者：Akihito Konishi ; Yasukazu Hirao ; Masayoshi Nakano ; Akihiro Shimizu ; Edith Botek ; Benot Champagne ; Daisuke Shiomi ; Kazunobu Sato ; Takeji Takui ; Kouzou Matsumoto ; Hiroyuki Kurata ; Takashi Kubo
- 刊名：Journal of the American Chemical Society
- 出版年：2010
- 出版时间：August 18, 2010
- 年：2010
- 卷：132
- 期：32
- 页码：11021-11023
- 全文大小：234K
- 年卷期：v.132,no.32(August 18, 2010)
- ISSN：1520-5126
文摘
A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.