Reactions of (E)-5-(Pyridin-4-yl-methyleneamino)isophthalic Acid (LH2) with Triorganotin Oxides and 鈭扖hloride. Formation of One-Dimensional- and Two-Dimensional-Coordination Polymers

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• 作者：Vadapalli Chandrasekhar ; Chandrajeet Mohapatra ; Ramesh K. Metre
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：October 2, 2013
• 年：2013
• 卷：13
• 期：10
• 页码：4607-4614
• 全文大小：654K
• 年卷期：v.13,no.10(October 2, 2013)
• ISSN：1528-7505

文摘

The reaction of (n-Bu₃Sn)₂O with (E)-5-(pyridin-4-yl-methyleneamino)isophthalic acid (LH₂) in a stoichiometric ratio of 1:1 resulted in the formation of a 2D coordination polymer [(n-Bu₃Sn)₂(渭-L)]_n (1). The structure of 1 contains a 36-membered macrocycle as its repeating building block. The reactions of Me₃SnCl or (Ph₃Sn)₂O with LH₂, on the other hand, result in the generation of [(Me₃Sn)₂(渭-L)(H₂O)]_n (a neutral 1D coordination polymer) (2) and [(Ph₃Sn)(渭-L)(Et₃NH)]_n (an anionic 1D coordination polymer) (3), respectively. Compounds 1鈥?b>3 show a rich supramolecular architecture in their solid state as a result of multiple secondary interactions.