Adsorption Characteristics of Activated Carbon for the Reclamation of Colored Effluents Containing Orange G and New Solid–Liquid Phase Equilibrium Model
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- 作者：R. Gopinathan ; Avijit Bhowal ; Chandrasekhar Garlapati
- 刊名：Journal of Chemical & Engineering Data
- 出版年：2017
- 出版时间：January 12, 2017
- 年：2017
- 卷：62
- 期：1
- 页码：558-567
- 全文大小：562K
- ISSN：1520-5134
文摘
Adsorption characteristics of activated carbon for the removal of orange G, an acid dye from aqueous solutions, have been investigated. The effect of initial dye concentration, temperature, and pH on the removal of orange G was investigated. The removal of orange G decreased from 95% to 82%, when the pH was increased from 2 to 12. The study of the effect of temperature and associated thermodynamic properties revealed the process of removal of dye is exothermic and spontaneous. Kinetic and mass transfer studies of the process were also carried out. The experimental data were used to develop a new solid–liquid phase equilibrium isotherm model. The average absolute relative deviation of the experimental data from the proposed model equation was 5.68%. In order to scale up the batch process for the removal of orange G, the concentration versus time data were analyzed to obtain mass transfer coefficient. The liquid-phase volumetric mass transfer coefficient (kLapL) was found to decrease from 0.008057 to 0.002827 s–1 when the initial concentration varied from 50 to 125 mg·L–1