Molecular-Beam Optical Stark and Zeeman Study of the [17.8]0+鈥揦1危+ (0,0) Band System of AuF
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- 作者：Timothy C. Steimle ; Ruohan Zhang ; Chengbing Qin ; Thomas D. Varberg
- 刊名：Journal of Physical Chemistry A
- 出版年：2013
- 出版时间：November 21, 2013
- 年：2013
- 卷：117
- 期：46
- 页码：11737-11744
- 全文大小：331K
- 年卷期：v.117,no.46(November 21, 2013)
- ISSN：1520-5215
文摘
The [17.8]0+鈥揦1危+ (0,0) band of gold monofluoride, AuF, has been recorded at a resolution of 40 MHz both field free and in the presence of a static electric and magnetic field. The observed Stark shifts were analyzed to determine the permanent electric dipole moment, 渭el, of 2.03 卤 0.05 D and 4.13 卤 0.02 D, for the [17.8]0+(v = 0) and X1危+(v = 0) states, respectively. The small magnetic tuning observed for the [17.8]0+(v = 0) state is attributed to rotational and magnetic field mixing with the [17.7]1 state and has been successfully modeled using an effective Hamiltonian for the 3螤 state. A comparison with the numerous published theoretical predictions is made.