Step-Economical Syntheses of Functional BODIPY-EDOT 蟺-Conjugated Materials through Direct C鈥揌 Arylation

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• 作者：Hui Chong ; Hsing-An Lin ; Mo-Yuan Shen ; Ching-Yuan Liu ; Haichao Zhao ; Hsiao-hua Yu
• 刊名：Organic Letters
• 出版年：2015
• 出版时间：July 2, 2015
• 年：2015
• 卷：17
• 期：13
• 页码：3198-3201
• 全文大小：267K
• ISSN：1523-7052

文摘

Palladium-catalyzed direct C鈥揌 arylations of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) with 3,4-ethylenedioxythiophene (EDOT) derivatives at relatively low temperature (60 掳C) provide moderate to good yields (47%鈥?2%) of products having potential applications in fluorescent bioimaging and organic optoelectronics.