Formation of Cocrystal Nanorods by Solid-State Reaction of Tetracyanobenzene in 9-Methylanthracene Molecular Crystal Nanorods

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• 作者：Rabih O. Al-Kaysi^&#8225 ; ; Astrid M. Mller^§ ; ; Robert J. Frisbee ; Christopher J. Bardeen*
• 刊名：Crystal Growth & Design
• 出版年：2009
• 出版时间：April 1, 2009
• 年：2009
• 卷：9
• 期：4
• 页码：1780-1785
• 全文大小：260K
• 年卷期：v.9,no.4(April 1, 2009)
• ISSN：1528-7505

文摘

The reaction of single-component molecular crystal nanorods with a second species to form cocrystal nanorods is described. Single-component crystalline nanorods, composed of 9-methylanthracene (9-MA), are grown in a porous anodic aluminum oxide template. These templated rods are then exposed to a suspension of 1,2,4,5-tetracyanobenzene (TCNB) in water, which slowly diffuses into the 9-MA rods over the course of days. The two species form a 1:1 charge-transfer complex within the rods, which are transformed from crystalline 9-MA into cocrystalline 9-MA/TCNB. The cocrystal nanorods are characterized by electron microscopy, X-ray diffraction, and optical spectroscopy, confirming their highly crystalline structure and the formation of the charge-transfer complex. Attempts to grow cocrystal nanorods directly from a mixed solution were unsuccessful, as were attempts to recreate the single crystal-to-crystal reaction in macroscopic crystals. This work demonstrates how organic nanostructures can support structure-preserving chemical transformations that are impossible in larger crystals.