文摘
In general, the chemistry of both 畏1-allyl and 畏3-allyl Pd complexes is extremely well understood; 畏1-allyls are nucleophilic and react with electrophiles, whereas 畏3-allyls are electrophilic and react with nucleophiles. In contrast, relatively little is known about the chemistry of metal complexes with bridging allyl ligands. In this work, we describe a more efficient synthetic methodology for the preparation of PdI-bridging allyl dimers and report the first studies of their stoichiometric reactivity. Furthermore, we show that these compounds can activate CO2 and that an N-heterocyclic carbene-supported dimer is one of the most active and stable catalysts reported to date for the carboxylation of allylstannanes and allylboranes with CO2.