“Molecular Nanoclusters”: A 2-nm-Sized {Mn29} Cluster with a Spherical Structure

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• 作者：Dimitris I. Alexandropoulos ; Adeline Fournet ; Luís Cunha-Silva ; George Christou ; Theocharis C. Stamatatos
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：December 5, 2016
• 年：2016
• 卷：55
• 期：23
• 页码：12118-12121
• 全文大小：282K
• ISSN：1520-510X

文摘

The comproportionation reaction between Mn^II and Mn^VII sources in the presence of 3,3-dimethylacrylic acid and azides has led to a new {Mn₂₉} molecular cluster with a spherical structure and dimensions of ∼2.2 nm, comparable in size to the smallest classical and magnetic nanoparticles.