Factors Impacting Electron Transfer in Cyano-Bridged {Fe2Co2} Clusters

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• 作者：Chunyang Zheng ; Juping Xu ; Zhixin Yang ; Jun Tao ; Dongfeng Li
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：October 19, 2015
• 年：2015
• 卷：54
• 期：20
• 页码：9687-9689
• 全文大小：228K
• ISSN：1520-510X

文摘

A cyano-bridged {Fe^III₂Co^II₂} complex exhibits reversible thermally and photoinduced intramolecular charge transfer. Its desolvated, MeOH-d₄, and other analogues were compared to disclose the impact factors on the electron-transfer behavior of these {Fe^III₂Co^II₂} clusters.