Paramagnetism of Aqueous Actinide Cations. Part II: Theoretical Aspects and New Measurements on An(IV)

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• 作者：Matthieu Autillo ; Laetitia Guerin ; Dominique Guillaumont ; Philippe Moisy ; Hélène Bolvin ; Claude Berthon
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：December 5, 2016
• 年：2016
• 卷：55
• 期：23
• 页码：12149-12157
• 全文大小：324K
• ISSN：1520-510X

文摘

The magnetic properties of actinide(IV) (An(IV)) cations are investigated in various solutions (HClO₄, HCl, and HNO₃) by the Evans NMR method. The magnetic susceptibilities measured in noncomplexing medium are compared with the previous studies, and the influence of the medium is verified with new measurements in complexing solutions. To rationalize these results, spin–orbit complete active space perturbation theory at second order calculations are performed on the free ions and on the aquo complexes to determine the nature of electronic states, the magnetic susceptibility, and the UV–visible–near-IR spectra. The different factors contributing to the An(IV) magnetic properties were identified. The ligand field effect on the magnetic behavior (Curie constant and temperature-independent susceptibilities) was analyzed by considering different solvation environments. These results indicate a significant effect of the zero-field splitting of the ground J manifold on the An(IV) magnetic susceptibility.