Zeolite-Promoted Oxidations of 1,1-Diarylethylenes
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  • 作者:Edward L. Clennan and Gui-lan Pan
  • 刊名:Organic Letters
  • 出版年:2003
  • 出版时间:December 25, 2003
  • 年:2003
  • 卷:5
  • 期:26
  • 页码:4979 - 4982
  • 全文大小:71K
  • 年卷期:v.5,no.26(December 25, 2003)
  • ISSN:1523-7052
文摘
The intrazeolite photooxygenations of four diarylethylenes have been examined. Several intermediates, including an epoxide, have been identifiedby comparison to independently synthesized samples. Aldehyde intermediates were shown to undergo intrazeolite Norrish type I cleavagesin competition with a novel new photooxygenation/autoxidation reaction.

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