An Unusual 3D Entangled Co(II) Coordination Polymer Directed by Ferromagnetic Molecular Building Block
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- 作者：Jian-Qiang Liu ; Bin Liu ; Yao-Yu Wang ; Ping Liu ; Guo-Ping Yang ; Rui-Ting Liu ; Qi-Zhen Shi ; Stuart R. Batten
- 刊名：Inorganic Chemistry
- 出版年：2010
- 出版时间：November 15, 2010
- 年：2010
- 卷：49
- 期：22
- 页码：10422-10426
- 全文大小：848K
- 年卷期：v.49,no.22(November 15, 2010)
- ISSN：1520-510X
文摘
A fascinating 3D entangled metal−organic framework, namely, {[Co2(bcp)2]·3H2O}n (1), was obtained through the solvothermal generation of flexible and long dicarboxylate (bcp) and metal salt. The crystal structure contains a 1D metal chain with bcp ligands wrapped around it in a wavy line and features an unusual entangled topological net. Furthermore, the magnetic behavior of 1 was also studied and indicated the existence of ferromagnetic interaction and long-range ordering character.