The addition of the SuperQuat enolate to five- and six-membered heterocyclic tert-butyl sulfinimines led to a high syn-selectivity of up to 99:1 in good to excellent yields. The reaction is tentatively proposed to proceed through an open-chain transition state with the presence of an 伪-heteroatom on the sulfinimine leading to high diastereoselectivities. The adducts were derivatized to 尾-amino esters and amides in a facile manner.