One-Dimensional Copper(I) Coordination Polymers Based on a Tridentate Thioether Ligand

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• 作者：Hing W. Yim ; Linh M. Tran ; Eric E. Pullen ; Daniel Rabinovich ; Louise M. Liable-Sands ; Thomas E. Concolino ; and Arnold L. Rheingold
• 刊名：Inorganic Chemistry
• 出版年：1999
• 出版时间：December 27, 1999
• 年：1999
• 卷：38
• 期：26
• 页码：6234 - 6239
• 全文大小：109K
• 年卷期：v.38,no.26(December 27, 1999)
• ISSN：1520-510X

文摘

The one-dimensional copper(I) coordination polymers Cu₃{MeSi(CH₂SMe)₃}₂X₃ (X = Cl, Br) and [{MeSi(CH₂SMe)₃}Cu(NCMe)]Y (Y = OSO₂CF₃, BF₄, PF₆) were readily obtained in very good to excellent yields (80-95%) by reacting CuX or [Cu(NCMe)₄]Y, respectively, with the tridentate thioether ligand MeSi(CH₂SMe)₃ inacetonitrile. The new complexes were characterized by a combination of analytical and spectroscopic techniques,including electrospray ionization mass spectrometry and, for the bromo and hexafluorophosphate derivatives,single-crystal X-ray diffraction. Both complexes exhibit one-dimensional chain structures with approximatelytetrahedral copper centers and bridging unidentate/bidentate thioether ligands.