Microwave-Assisted Synthesis of Functionalized Shvo-Type Complexes

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• 作者：Cristiana Cesari ; Letizia Sambri ; Stefano Zacchini ; Valerio Zanotti ; Rita Mazzoni
• 刊名：Organometallics
• 出版年：2014
• 出版时间：June 9, 2014
• 年：2014
• 卷：33
• 期：11
• 页码：2814-2819
• 全文大小：330K
• 年卷期：v.33,no.11(June 9, 2014)
• ISSN：1520-6041

文摘

A simple and expeditious microwave-assisted procedure for the synthesis of a variety of Shvo-type ruthenium complexes has been developed by reacting Ru₃(CO)₁₂ with variously functionalized tetraarylcyclopentadienones under microwave irradiation in MeOH. Ligand precursors have also been prepared under microwave heating by a bis-aldol condensation of 1,3-diphenylacetone with variously functionalized aromatic diketones. All the reactions were very fast and clean, leading to good yields and purities.