Synthesis and Star/Linear Topology Transformation of a Mechanically Linked ABC Terpolymer

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• 作者：Hiroki Sato ; Daisuke Aoki ; Toshikazu Takata
• 刊名：ACS Macro Letters
• 出版年：2016
• 出版时间：June 21, 2016
• 年：2016
• 卷：5
• 期：6
• 页码：699-703
• 全文大小：379K
• 年卷期：0
• ISSN：2161-1653

文摘

The synthesis of an ABC star terpolymer containing one polymer chain connected mechanically through a rotaxane linkage and its topology transformation to a linear structure are reported. Pseudo[2]rotaxane, which was designed as the key trifunctional species for the star polymer synthesis, comprised a sec-ammonium axle with ethynyl and hydroxy groups and a crown ether wheel with a trithiocarbonate group. Stepwise polymer connections to the pseudo[2]rotaxane using the three groups afforded a rotaxane-linked ABC star terpolymer. The topology transformation from star to linear by the removal of the attractive interaction between the axle and wheel components yielded a linear ABC terpolymer via the wheel shifting to the axle end. The spectroscopic and solution property changes clearly indicated the occurrence of the polymer topology change.