Acidification and Buffering Mechanisms in Acid Sulfate Soil Wetlands of the Murray-Darling Basin, Australia
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- 作者：Fiona Glover ; Kerry L. Whitworth ; Peter Kappen ; Darren S. Baldwin ; Gavin N. Rees ; John A. Webb ; Ewen Silvester
- 刊名：Environmental Science & Technology
- 出版年：2011
- 出版时间：April 1, 2011
- 年：2011
- 卷：45
- 期：7
- 页码：2591-2597
- 全文大小：894K
- 年卷期：v.45,no.7(April 1, 2011)
- ISSN：1520-5851
文摘
The acid generation mechanisms and neutralizing capacities of sulfidic sediments from two inland wetlands have been studied in order to understand the response of these types of systems to drying events. The two systems show vastly different responses to oxidation, with one (Bottle Bend (BB) lagoon) having virtually no acid neutralizing capacity (ANC) and the other (Psyche Bend (PB) lagoon) an ANC that is an order of magnitude greater than the acid generation potential. While BB strongly acidifies during oxidation the free acid generation is less than that expected from the measured proton production and consumption processes, with additional proton consumption attributed to the formation of an acid-anion (chloride) FeIII (oxyhydr)oxide product, similar to akagan茅ite (Fe(OH)2.7Cl0.3). While such products can partially attenuate the acidification of these systems, resilience to acidification is primarily imparted by sediment ANC.