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• 作者：Debajyoti Ghoshal ; Tapas Kumar Maji ; Golam Mostafa ; Tian-Huey Lu ; and Nirmalendu Ray Chaudhuri
• 刊名：Crystal Growth & Design
• 出版年：2003
• 出版时间：January 2003
• 年：2003
• 卷：3
• 期：1
• 页码：9 - 11
• 全文大小：314K
• 年卷期：v.3,no.1(January 2003)
• ISSN：1528-7505

文摘

A one pot reaction of MnCl₂, acetylene dicarboxylate (C₄O₄^2-), and 1,2-bis(4-pyridyl)ethane (bpe) leads to acompound formulated as [{Mn(bpe)(H₂O)₄}(C₄O₄)·4.5H₂O] and has been shown by single crystal structure analysis to bea three-dimensional network with hexagonal and rhombohedral channels encapsulating C₄O₄^2- and water molecules,constructed by the one-dimensional "sinusoidal" [Mn(bpe)(H₂O)₄]_n²⁺ cationic chains through extensive hydrogen-bondingand - interactions.