Structural, Spectroscopic, and Magnetic Properties of Eu3+-Doped GdVO4 Nanocrystals Synthesized by a Hydrothermal Method

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• 作者：Agata Szczeszak ; Tomasz Grzyb ; Zbigniew 艢niadecki ; Nina Andrzejewska ; Stefan Lis ; Micha艂 Matczak ; Grzegorz Nowaczyk ; Stefan Jurga ; Bogdan Idzikowski
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：December 1, 2014
• 年：2014
• 卷：53
• 期：23
• 页码：12243-12252
• 全文大小：895K
• ISSN：1520-510X

文摘

New interesting aspects of the spectroscopic properties, magnetism, and method of synthesis of gadolinium orthovanadates doped with Eu³⁺ ions are discussed. Gd_1鈥?i>xEu_xVO₄ (x = 0, 0.05, 0.2) bifunctional luminescent materials with complex magnetic properties were synthesized by a microwave-assisted hydrothermal method. Products were formed in situ without previous precipitation. The crystal structures and morphologies of the obtained nanomaterials were analyzed by X-ray diffraction and transmission and scanning electron microscopy. Crystallographic data were analyzed using Rietveld refinement. The products obtained were nanocrystalline with average grain sizes of 70鈥?0 nm. The qualitative and quantitative elemental composition as well as mapping of the nanocrystals was proved using energy-dispersive X-ray spectroscopy. The spectroscopic properties of red-emitting nanophosphors were characterized by their excitation and emission spectra and luminescence decays. Magnetic measurements were performed by means of vibrating sample magnetometry. GdVO₄ and Gd_0.8Eu_0.2VO₄ exhibited paramagnetic behavior with a weak influence of antiferromagnetic couplings between rare-earth ions. In the substituted sample, an additional magnetic contribution connected with the population of low-lying excited states of europium was observed.