Rhombohedrally Distorted γ-Brasses Cr1−xFexGa

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• 作者：Hyunjin Ko ; Olivier Gourdon ; Delphine Gout ; Eun-Deok Mun ; Srinivasa Thimmaiah ; Gordon J. Miller
• 刊名：Inorganic Chemistry
• 出版年：2010
• 出版时间：December 20, 2010
• 年：2010
• 卷：49
• 期：24
• 页码：11505-11515
• 全文大小：1004K
• 年卷期：v.49,no.24(December 20, 2010)
• ISSN：1520-510X

文摘

A series of rhombohedrally distorted γ-brass structures containing a mixture of magnetically active 3d elements, Cr and Fe, Cr_1−xFe_xGa, is investigated crystallographically. These structures consist of chains of trans-face-sharing Ga-centered transition metal icosahedra. Neutron powder diffraction specifically on Cr_0.5Fe_0.5Ga, which could be prepared as a single phase material, gave lattice constants (11 K) a = 12.5172(2) Å and c = 7.8325(2) Å and a refined composition of Cr_0.502(6)Fe_0.498Ga = Cr_6.523Fe_6.477Ga₁₃ and revealed partial ordering of Cr and Fe atoms among three crystallographic sites. Magnetic susceptibility and magnetization studies of Cr_0.5Fe_0.5Ga showed the onset of magnetic ordering at ca. 25 K. Theoretical calculations suggested both site-energy and bond-energy factors influencing the Cr/Fe distribution. Heteroatomic interactions significantly affect exchange interactions and create low local magnetic moments. Models created to mimic Cr_0.5Fe_0.5Ga showed ferromagnetic Fe−Fe and antiferromagnetic Cr−Fe interactions, with an overall ferrimagnetic ordering.