New Volatile Strontium and Barium Imidazolate Complexes for the Deposition of Group 2 Metal Oxides

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• 作者：John A. T. Norman ; Melanie Perez ; M. S. Kim ; Xinjian Lei ; Sergei Ivanov ; Agnes Derecskei-Kovacs ; Laura Matz ; Iain Buchanan ; Arnold L. Rheingold
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：December 19, 2011
• 年：2011
• 卷：50
• 期：24
• 页码：12396-12398
• 全文大小：244K
• 年卷期：v.50,no.24(December 19, 2011)
• ISSN：1520-510X

文摘

We report the synthesis, characterization, and experimental density function theory-derived properties of new volatile strontium and barium imidazolate complexes, which under atomic layer deposition conditions using ozone as a reagent can deposit crystalline strontium oxide at 375 掳C.