Aromatic Nucleophilic Substitution (SNAr) of meso-Nitroporphyrin with Azide and Amines as an Alternative Metal Catalyst Free Synthetic Approach To Obtain meso-N-Substit
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- 作者：Charles H. Devillers ; Seydou Hebi茅 ; Dominique Lucas ; H茅l猫ne Cattey ; S茅bastien Cl茅ment ; S茅bastien Richeter
- 刊名：Journal of Organic Chemistry
- 出版年：2014
- 出版时间：July 18, 2014
- 年：2014
- 卷：79
- 期：14
- 页码：6424-6434
- 全文大小：592K
- ISSN：1520-6904
文摘
Aromatic nucleophilic substitution reaction of the nitro group of meso-nitroporphyrins with azide and various amines was achieved and represents an alternative procedure to C鈥揘 coupling reactions usually needed to obtain such meso-N-substituted porphyrins in good yields.