NH/PH Isomerization and a Lewis Pair for Carbon Dioxide Capture

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• 作者：Brian M. Barry ; Diane A. Dickie ; Luke J. Murphy ; Jason A. C. Clyburne ; Richard A. Kemp
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：August 5, 2013
• 年：2013
• 卷：52
• 期：15
• 页码：8312-8314
• 全文大小：204K
• 年卷期：v.52,no.15(August 5, 2013)
• ISSN：1520-510X

文摘

Bis(di-i-propylphosphino)amine 1 reacts with B(C₆F₅)₃ to form an adduct with concomitant N/P H-isomerization. This species reacts smoothly with carbon dioxide. An attempt to prepare an anionic derivative resulted in the formation of a novel heterocycle derived from the PNP ligand and B(C₆F₅)₃.