Design of Novel Photoinitiators for Radical and Cationic Photopolymerizations under Near UV and Visible LEDs (385, 395, and 405 nm).

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• 作者：Jing Zhang ; Michel Frigoli ; Fr茅d茅ric Dumur ; Pu Xiao ; Laura Ronchi ; Bernadette Graff ; Fabrice Morlet-Savary ; Jean Pierre Fouassier ; Didier Gigmes ; Jacques Lalev茅e
• 刊名：Macromolecules
• 出版年：2014
• 出版时间：May 13, 2014
• 年：2014
• 卷：47
• 期：9
• 页码：2811-2819
• 全文大小：513K
• 年卷期：v.47,no.9(May 13, 2014)
• ISSN：1520-5835

文摘

Three novel photoinitiators, namely (2,2鈥?bithiophen-5-yl)(4-(N,N鈥?dimethylaminophenyl)ketone, 5,10-dimethoxybenzo[j]fluoranthene and 6,6鈥?(((1E,1鈥?i>E)-(2,5-bis(octyloxy)-1,4-phenylene)bis(ethene-2,1-diyl))bis(4,1-phenylene))bis(1,3,5-triazine-2,4-diamine) applicable to different near UV or visible LEDs (385 nm, 395 nm, 405 nm or cold white LED) have been developed. When incorporated into multicomponent photoinitiating systems PISs (in the presence of iodonium salt (and optionally N-vinyl carbazole) or amine/alkyl halide couples), they exhibit quite excellent photoinitiating abilities for the cationic polymerization CP of epoxides or the free radical polymerization FRP of methacrylates under air. Compared to the corresponding camphorquinone-based systems, the newly developed photoinitiating systems display noticeably higher polymerization efficiencies under air (epoxide conversions = 31鈥?5% vs 0%, halogen lamp exposure; methacrylate conversion = 56鈥?6% vs 0鈥?%, LED irradiation). These systems are very interesting to overcome the oxygen inhibition. The photochemical mechanisms have been studied by steady state photolysis, electron spin resonance spin trapping, fluorescence, cyclic voltammetry, and laser flash photolysis techniques.