Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes

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• 作者：Wen-Xue Niu ; Tao Wang ; Qin-Qing Hou ; Zi-Yang Li ; Xiao-Ping Cao ; Dietmar Kuck
• 刊名：Journal of Organic Chemistry
• 出版年：2010
• 出版时间：October 1, 2010
• 年：2010
• 卷：75
• 期：19
• 页码：6704-6707
• 全文大小：758K
• 年卷期：v.75,no.19(October 1, 2010)
• ISSN：1520-6904

文摘

The synthesis of several inherently chiral tribenzotriquinacenes (TBTQs) bearing one single mono- or difunctionalized aromatic nucleus and the optical resolution of one of these derivatives, a TBTQ-based salicylic acid (11), are described for the first time. Efficient access to enantiopure, inherently chiral tribenzotriquinacenes may lay a foundation for studies of novel container compounds, supramolecular aggregation, chiral recognition, and asymmetric catalysis.