Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly
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- 作者：Bhaskar Jyoti Sarmah ; Dipak Kumar Dutta*
- 刊名：Crystal Growth & Design
- 出版年：2009
- 出版时间：April 1, 2009
- 年：2009
- 卷：9
- 期：4
- 页码：1643-1645
- 全文大小：200K
- 年卷期：v.9,no.4(April 1, 2009)
- ISSN：1528-7505
文摘
The dimeric units [RhCl2(Hhmp)(hmp)]2, where Hhmp and hmp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic π-π and CH/-π interactions to generate a nanoporous supramolecular structure exhibiting permanent porosity and selective adsorption properties.