Halogenated Xenon Cyanides ClXeCN, ClXeNC, and BrXeCN

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• 作者：Teemu Arppe ; Leonid Khriachtchev ; Antti Lignell ; Alexandra V. Domanskaya ; Markku R盲s盲nen
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：April 2, 2012
• 年：2012
• 卷：51
• 期：7
• 页码：4398-4402
• 全文大小：197K
• 年卷期：v.51,no.7(April 2, 2012)
• ISSN：1520-510X

文摘

We report on the preparation and characterization of three new noble-gas molecules ClXeCN, ClXeNC, and BrXeCN. These molecules are synthesized by 193 nm photolysis and thermal annealing of ClCN and BrCN in a xenon matrix. The absorption spectra are measured in the mid- and far-infrared regions, and the assignment is supported by isotope substitution and quantum chemical calculations at the B3LYP and MP2 levels of theory. The present results demonstrate a way to prepare other noble-gas molecules of this type.