Precision Multisegmented Macromolecular Lineups: A Display of Unique Control over Backbone Structure and Functionality

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• 作者：Frank Driessen ; Filip E. Du Prez ; Pieter Espeel
• 刊名：ACS Macro Letters
• 出版年：2015
• 出版时间：June 16, 2015
• 年：2015
• 卷：4
• 期：6
• 页码：616-619
• 全文大小：210K
• ISSN：2161-1653

文摘

A practical synthesis of unique, precisely decorated, multisegmented block copolymers was elaborated via amine-thiol鈥揺ne conjugation. By mixing the thiolactone-acrylate heterotelechelic precursor polymer with selected amines, a library of multisegmented species was obtained, featuring a high level of control over backbone structure and spatial arrangement of side chain residues. Ranging from glycosylated to amphiphilic materials, these macromolecular lineups have been analyzed by LCxSEC DOSY-NMR, and DLS, revealing the particular properties of these macromolecular structures.