Dry Reforming of Methane with Dielectric Barrier Discharge and Ferroelectric Packed-Bed Reactors

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• 作者：Wei-Chieh Chung ; Kuan-Lun Pan ; How-Ming Lee ; Moo-Been Chang
• 刊名：Energy & Fuels
• 出版年：2014
• 出版时间：December 18, 2014
• 年：2014
• 卷：28
• 期：12
• 页码：7621-7631
• 全文大小：726K
• ISSN：1520-5029

文摘

A hybrid plasma catalytic system consisting of a dielectric barrier discharge (DBD) reactor and relaxor ferroelectrics is investigated for syngas generation via the carbon dioxide reforming of methane. The study tests three kinds of packing materials, including two relaxor ferroelectrics BaZr_0.75T_0.25O₃ (BZT; 蔚_r = 149), BaFe_0.5Nb_0.5O₃ (BFN; 蔚_r = 2025), and glass beads (蔚_r = 3鈥?). The BFN and BZT packed-bed DBD reactors achieve higher CO₂ and CH₄ conversions and better energy efficiencies for syngas production than the DBD. On the contrary, the DBD packed with glass beads achieves lower conversions and energy efficiencies than the DBD. In terms of packings filled in a DBD reactor, there is a trade-off between an enhancement of the electric field strength and a reduction of the gas retention time. It is interesting that the conversions are increased with the increase of the dielectric constant of the packings tested in the study. Overall, a relaxor ferroelectric with a high dielectric constant is a good candidate for constituting the packed-bed DBDs. The finding is beneficial to further development of a plasma-based technique for the dry reforming of methane (DRM).