Modern and Fossil Contributions to Polycyclic Aromatic Hydrocarbons in PM2.5 from North Birmingham, Alabama in the Southeastern U.S.

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• 作者：Li Xu ; Mei Zheng ; Xiang Ding ; Eric S. Edgerton ; Christopher M. Reddy
• 刊名：Environmental Science & Technology (ES&T)
• 出版年：2012
• 出版时间：February 7, 2012
• 年：2012
• 卷：46
• 期：3
• 页码：1422-1429
• 全文大小：345K
• 年卷期：v.46,no.3(February 7, 2012)
• ISSN：1520-5851

文摘

Analyzing the radiocarbon (¹⁴C) content of polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulate matter can provide estimates on the source contributions from biomass burning versus fossil fuel. The relative importance of these two sources to ambient PAHs varies considerably across regions and even countries, and hence there is a pressing need to apportion these sources. In this study, we advanced the radiocarbon analysis from bulk carbon to compound class specific radiocarbon analysis (CCSRA) to determine 螖¹⁴C and 未¹³C values of PAHs in PM_2.5 samples for investigating biomass burning and fossil fuel source contributions to PAHs from one of the Southeastern Aerosol Research and Characterization (SEARCH) sites in North Birmingham (BHM), Alabama during winter (December 2004-February 2005) and summer (June-August 2005) by accelerator mass spectrometry. To compare our ambient samples to known sources, we collected and analyzed fenceline samples from the vicinity of a coke plant in BHM. As expected, PAHs from the coke plant fenceline samples had very low radiocarbon levels. Its 螖¹⁴C varied from 鈭?90 to 鈭?70鈥? indicating that 97 to 99% were of fossil source. PAHs in the ambient PM_2.5 had 螖¹⁴C from 鈭?68 to 鈭?11 鈥? indicating that 92鈥?7% of PAHs were from fossil fuel combustion. These levels indicated the dominance of fossil sources of ambient PAHs. The radiocarbon level of ambient PAHs was higher in winter than in summer. Winter samples exhibited depleted 未¹³C value and enriched 螖¹⁴C value because of the increased contribution of PAHs from biomass burning source. However, biomass burning contributed more to heavier PAHs (modern source accounting for 6鈥?%) than lighter ones with a modern contribution of 3%.