Fast Pyrolysis of Lignin Using a Pyrolysis Centrifuge Reactor

详细信息    查看全文

• 作者：Trung Ngoc Trinh ; Peter Arendt Jensen ; Zsuzsa S谩rossy ; Kim Dam-Johansen ; Niels Ole Knudsen ; Hanne Risbjerg S酶rensen ; Helge Egsgaard
• 刊名：Energy & Fuels
• 出版年：2013
• 出版时间：July 18, 2013
• 年：2013
• 卷：27
• 期：7
• 页码：3802-3810
• 全文大小：415K
• 年卷期：v.27,no.7(July 18, 2013)
• ISSN：1520-5029

文摘

Fast pyrolysis of lignin from an ethanol plant was investigated on a lab scale pyrolysis centrifuge reactor (PCR) with respect to pyrolysis temperature, reactor gas residence time, and feed rate. A maximal organic oil yield of 34 wt % dry basis (db) (bio-oil yield of 43 wt % db) is obtained at temperatures of 500鈥?50 掳C, reactor gas residence time of 0.8 s, and feed rate of 5.6 g/min. Gas chromatography mass spectrometry and size-exclusion chromatography were used to characterize the chemical properties of the lignin oils. Acetic acid, levoglucosan, guaiacol, syringols, and p-vinylguaiacol are found to be major chemical components in the lignin oil. The maximal yields of 0.62, 0.67, and 0.38 wt % db were obtained for syringol, p-vinylguaiacol, and guaiacol, respectively. The reactor temperature effect was investigated in a range of 450鈥?00 掳C and has a considerable effect on the observed chemical components and molecular mass distribution of the lignin oils. The obtained lignin oil has a very different components composition when compared to a beech wood oil.