Osmium-Promoted Dehydrogenation of Amine鈥揃oranes and B鈥揌 Bond Activation of the Resulting Amino鈥揃oranes

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• 作者：Miguel A. Esteruelas ; Israel Fern谩ndez ; Ana M. L贸pez ; Malka Mora ; Enrique O帽ate
• 刊名：Organometallics
• 出版年：2014
• 出版时间：March 10, 2014
• 年：2014
• 卷：33
• 期：5
• 页码：1104-1107
• 全文大小：270K
• 年卷期：v.33,no.5(March 10, 2014)
• ISSN：1520-6041

文摘

The five-coordinate osmium complex OsH(SH)(CO)(PⁱPr₃)₂, containing an electrophilic center bonded to the soft hydrogen sulfide ligand, promotes dehydrogenation of amine鈥揵oranes and captures the amino鈥揵orane products, forming hydrogenaminothioborate complexes.