Optical Behavior of Conjugated Pt-Containing Polymetallaynes Exposed to Gamma-Ray Radiation Doses

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• 作者：Augusto Batagin-Neto ; Erika S. Bronze-Uhle ; David M. Fernandes ; Ilaria Fratoddi ; Iole Venditti ; Franco Decker ; Enrico Bodo ; Maria Vittoria Russo ; Carlos F. O. Graeff
• 刊名：Journal of Physical Chemistry B
• 出版年：2011
• 出版时间：June 30, 2011
• 年：2011
• 卷：115
• 期：25
• 页码：8047-8053
• 全文大小：925K
• 年卷期：v.115,no.25(June 30, 2011)
• ISSN：1520-5207

文摘

The effect of ⁶⁰Co 纬 irradiation on the absorption and emission spectra of the organometallic polymer [鈭扨t(PBu₃)₂鈥擟鈮鈥擟₆H₄鈥擟₆H₄鈥擟鈮鈭抅_n (Pt-DEBP) in chloroform and toluene solutions for dosimetry applications has been studied. The system Pt-DEBP/chloroform can be used for dosimetric applications in two different ways: (i) monitoring of absorption spectra changes for higher doses (higher than 1 Gy), and (ii) monitoring of emission spectra changes for low doses (below 1 Gy). The response of the polymer solution to 纬 ray doses has been interpreted with the aid of theoretical studies based on time dependent density functional theory (TD-DFT) calculations on the absorption bands of a model complex and of the possible fragments coming from the degradation of the polymer backbone. It has been proposed that the observed changes are promoted by the attack of radicals, from the radiolysis of the solvent, on the polymer triple bonds.