Allylic Phosphinates via Palladium-Catalyzed Allylation of H-Phosphinic Acids with Allylic Alcohols

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• 作者：La&euml ; titia Coudray ; Karla Bravo-Altamirano ; Jean-Luc Montchamp
• 刊名：Organic Letters
• 出版年：2008
• 出版时间：March 20, 2008
• 年：2008
• 卷：10
• 期：6
• 页码：1123 - 1126
• 全文大小：98K
• 年卷期：v.10,no.6(March 20, 2008)
• ISSN：1523-7052

文摘

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Abstract A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly withallylic alcohols to produce P-allylated disubstituted phosphinic acids.