Nanostar and Nanonetwork Crystals Fabricated by in Situ Nanoparticlization of Fully Conjugated Polythiophene Diblock Copolymers
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- 作者：In-Hwan Lee ; Pitchamuthu Amaladass ; Ki-Young Yoon ; Suyong Shin ; Yong-Jae Kim ; Inhye Kim ; Eunji Lee ; Tae-Lim Choi
- 刊名：Journal of the American Chemical Society
- 出版年：2013
- 出版时间：November 27, 2013
- 年：2013
- 卷：135
- 期：47
- 页码：17695-17698
- 全文大小：284K
- 年卷期：v.135,no.47(November 27, 2013)
- ISSN：1520-5126
文摘
Nanostar and nanonetwork crystals were prepared from fully conjugated poly(3-(2-ethylhexyl)thiophene)-block-polythiophene (P3EHT-b-PT) via a simple INCP process. The structural conformation of the nanocrystals was investigated in detail, revealing that with an increase in the block length of PT, the morphology of the nanocrystals changed from nanospheres to nanorods, nanostars, and to nanonetworks.